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Indexed by:期刊论文

Date of Publication:2008-01-01

Journal:JOURNAL OF COORDINATION CHEMISTRY

Included Journals:SCIE

Volume:61

Issue:12

Page Number:1856-1861

ISSN No.:0095-8972

Key Words:diiron complex; iron-only hydrogenase; ruthenium photosensitizer; trinuclear complex

Abstract:An NH(2)-functionlized [Fe(2)S(2)] model complex of the iron-only hydrogenase active site was covalently linked to the tris( bipyridine) ruthenium photosensitizer. The [RuFeFe] trinuclear complex 1 was characterized by MS, IR, UV-vis, (1)H & (13)C NMR spectra. A quasi-reversible reduction peak at - 1.41V versus Ag/Ag(+) for the Fe(I)Fe(I)/Fe(I)Fe(0) process is observed in the cyclic voltammogram of 1.