Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2006-03-20

Journal: JOURNAL OF COORDINATION CHEMISTRY

Included Journals: SCIE

Volume: 59

Issue: 5

Page Number: 475-484

ISSN: 0095-8972

Key Words: manganese complex; rhenium complex; heterobinuclear complex; chiral salen ligand; pyrrolidine; light-driven catalyst

Abstract: Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied.