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Synthesis of chiral salen Mn(III) complexes covalently linked to Re(I)-based photosensitizers

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Indexed by:期刊论文

Date of Publication:2006-03-20

Journal:JOURNAL OF COORDINATION CHEMISTRY

Included Journals:SCIE

Volume:59

Issue:5

Page Number:475-484

ISSN No.:0095-8972

Key Words:manganese complex; rhenium complex; heterobinuclear complex; chiral salen ligand; pyrrolidine; light-driven catalyst

Abstract:Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied.

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