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Indexed by:期刊论文

Date of Publication:2006-03-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE

Volume:9

Issue:3

Page Number:290-292

ISSN No.:1387-7003

Key Words:hydrogenases; furan; diiron azadithiolate; proton reduction potential

Abstract:A new biomimetic model of the active site of Fe-only hydrogenase [{(mu-SCH2)(2)N(2-C4H3O)} Fe-2(CO)(6)] (6) was synthesized and characterized by IR, H-1, C-13 NMR spectroscopy. The butterfly based core structure was also confirmed by X-ray diffraction. The electrochemistry data indicated that the reductive potential at -1.13 V versus Fc/Fc(+) by HClO4 is the lowest of that reported. (C) 2005 Elsevier B.V. All rights reserved.