Release Time:2019-03-10  Hits:

Indexed by: Journal Article

Date of Publication: 2006-03-01

Journal: INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals: SCIE

Volume: 9

Issue: 3

Page Number: 290-292

ISSN: 1387-7003

Key Words: hydrogenases; furan; diiron azadithiolate; proton reduction potential

Abstract: A new biomimetic model of the active site of Fe-only hydrogenase [{(mu-SCH2)(2)N(2-C4H3O)} Fe-2(CO)(6)] (6) was synthesized and characterized by IR, H-1, C-13 NMR spectroscopy. The butterfly based core structure was also confirmed by X-ray diffraction. The electrochemistry data indicated that the reductive potential at -1.13 V versus Fc/Fc(+) by HClO4 is the lowest of that reported. (C) 2005 Elsevier B.V. All rights reserved.