Indexed by:期刊论文

Date of Publication:2014-02-01

Journal:ENERGY CONVERSION AND MANAGEMENT

Included Journals:SCIE、EI

Volume:78

Page Number:253-259

ISSN No.:0196-8904

Key Words:Catalyst; Glycerol steam reforming; Deactivation; Kinetics

Abstract:In this study, the activity of Ni-Cu-Al based catalyst for renewable hydrogen production from glycerol steam reforming has been evaluated in a continuous flow fixed-bed reactor under atmospheric pressure at 500-600 degrees C. The catalyst synthesized by the co-precipitation method with rising pH technique was characterized by the elemental analysis, Brenauer-Emmett-Teller (N-2-BET) adsorption method, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM) and thermogravimetric analysis (TGA). The thermodynamic analysis for glycerol steam reforming was conducted by using a non-stoichiometric methodology based on the minimization of Gibbs free energy. The obtained results revealed that the great quantity of hydrogen is produced at excess water and the formations of CH4 and CO in the glycerol steam reforming were almost negligible. The deactivation of catalyst due to the formation of carbon residues was observed. The carbons removal was measured by TGA experiment during medium temperature oxidation conditions. The kinetics on glycerol steam reforming was described by means of the separability concept of reaction rate law and deactivation model, and the kinetic parameters were calculated. (C) 2013 Elsevier Ltd. All rights reserved.