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Indexed by:期刊论文

Date of Publication:2012-10-12

Journal:POLYMER

Included Journals:SCIE、EI、Scopus

Volume:53

Issue:22

Page Number:5197-5207

ISSN No.:0032-3861

Key Words:Positive temperature coefficient; Self-heating; Tunnel effect

Abstract:A new approach for positive temperature coefficient (PTC) effect of resistivity for polymer-filler composites by self-heating and external forced heating was proposed, based on SEM. ESR and positron annihilation in terms of tunnel effect of electrons through polymer matrix between neighboring short carbon fibers (CFs). The CF content as fillers in polymer matrix was fixed at the concentration slightly higher than the percolation threshold. The fitting between theoretical resistivity calculated by tunnel current density and experimental resistivity indicated that transport hindrance of electrons with elevating temperature was attributed to a drastic increase in potential barrier height resulted from free volume expansion in polymer matrix as well as air volume expansion between neighboring CFs. Different from the well-known concept, this effect was much more predominant than an increase in potential barrier width. The proposed quantitative analysis also satisfied time-dependence of resistivity at a fixed applied electric field and an increase in conductivity by gamma-ray irradiation. (c) 2012 Elsevier Ltd. All rights reserved.