location： Current position: Home >> Scientific Research >> Paper Publications

Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo3S4Pd(eta(3)-allyl)] Clusters

Hits:

Indexed by:期刊论文

Date of Publication:2010-06-18

Journal:ORGANIC LETTERS

Included Journals:SCIE、PubMed、Scopus

Volume:12

Issue:12

Page Number:2726-2729

ISSN No.:1523-7060

Abstract:A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)(3)(mu(3)center dot S)(4)Pd(eta(3)-allyl)][PF6](2) clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the alpha- or gamma-position only linear products are obtained.

Pre One:Mild and Highly Enantioselective Vinylogous Aldol Reaction of Brassard's Diene with Aromatic Aldehydes by Combined Lewis Acid Catalyst

Next One:Catalytic Asymmetric Conjugate Addition of Simple Alkyl Thiols to α,β-Unsaturated N-Acylated Oxazolidin-2-ones with Bifunctional Catalysts
Recommended Ph.D.Supervisor Recommended MA Supervisor Institutional Repository Personal Page

Address: No.2 Linggong Road, Ganjingzi District, Dalian City, Liaoning Province, P.R.C., 116024

Click : times
  • MOBILE Version
    •
    Open time:..
    The Last Update Time:..

    Mobile phone sweep