Hits:
Indexed by:期刊论文
Date of Publication:2007-01-01
Journal:JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Included Journals:SCIE
Volume:11
Issue:5-6
Page Number:463-469
ISSN No.:1088-4246
Key Words:Cu(III) corrole; [Ru(bpy)(3)](2+); OEC; photosystem II; water oxidation
Abstract:A novel binuclear Ru-Cu complex, composed of a copper(III)-corrole and a ruthenium(II) tris(bipyridine) moicty linked by an amide bond, has been synthesized and characterized by H-1 NMR, UV-vis and mass spectrometry. The steady-state emission and the electrochemical properties were investigated. Compared to the parent [Ru(bpy)(3)](2+), the emission-of the desired complex was substantially quenched when the MLCT of [Ru(bpy)(3)](2+) was selectively photoexcited. Copyright (C) 2007. Society of Porphyrins & Phthalocyanines.
Pre One:Synthesis and characterisation of a high valent dinuclear Mn(III,III) complex of a triphenolate ligand [N4O3](3-) with two extra functional groups
Next One:Synthesis and photophysical and electrochemical study of tyrosine covalently linked to high-valent copper(III) and manganese(IV) complexes