Release Time:2019-10-22  Hits:

Indexed by: Journal Article

Date of Publication: 2004-01-01

Journal: JOURNAL OF CHEMICAL RESEARCH-S

Included Journals: SCIE

Issue: 1

Page Number: 57-58

ISSN: 0308-2342

Key Words: dinuclear manganese; ligand design; artificial photosynthesis

Abstract: A new high valent complex [Mn-2(III,III)L(mu-OAc)(2)].PF6 7 was prepared, where L was the tri-anion of 2,6-Bis {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl}-4-methylphenol which contained two additional phenolate groups and two tert-butyl groups compared to its parent [Mn-2(II, II)(bpmp)(mu-OAc)(2)].PF6. These improvements narrowed the disparity between the new model and (Mn)(4) cluster (OEC in nature).