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Indexed by:期刊论文

Date of Publication:2004-01-01

Journal:JOURNAL OF CHEMICAL RESEARCH-S

Included Journals:SCIE

Issue:1

Page Number:57-58

ISSN No.:0308-2342

Key Words:dinuclear manganese; ligand design; artificial photosynthesis

Abstract:A new high valent complex [Mn-2(III,III)L(mu-OAc)(2)].PF6 7 was prepared, where L was the tri-anion of 2,6-Bis {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl}-4-methylphenol which contained two additional phenolate groups and two tert-butyl groups compared to its parent [Mn-2(II, II)(bpmp)(mu-OAc)(2)].PF6. These improvements narrowed the disparity between the new model and (Mn)(4) cluster (OEC in nature).