Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-08-01

Journal: JOURNAL OF CRYSTAL GROWTH

Included Journals: Scopus、EI、SCIE

Volume: 399

Page Number: 43-48

ISSN: 0022-0248

Key Words: Purification; Stirring; Solidification; Alloys

Abstract: A low-cost and high-efficiency method to purify Si directly from cheap MG-Si at low temperature was proposed and demonstrated in this paper, which used power frequency rotating magnetic field (RMF) to separate the primary Si from a hypereutectic Al-Si alloy and was followed by the acid peeling. The separation mechanism was based on the flow characteristic of melt under RMF and the cooling condition of the liquid metal. A Si-rich layer with Si content of 65-59 wt% was formed in the periphery of alloy, while the inner microstructure of the alloy was mainly the Al-Si eutectic structure. The refilled silicon was collected after aqua regia leaching, and had much fewer typical impurities (Fe, Ti, Ca, B, P) than those in MG-Si, and the metallic impurities besides Al had removal fraction higher than 98%, which is mainly ascribed to the segregation effect of Al-30Si alloy during solidification under RMF. (C) 2014 Elsevier B.V. All rights reserved.