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Indexed by:期刊论文

Date of Publication:2018-11-01

Journal:SOLAR ENERGY

Included Journals:SCIE

Volume:174

Page Number:225-230

ISSN No.:0038-092X

Key Words:Metal-organic frameworks; Co@N-doped carbon nanotubes; Dye-sensitized solar cells; Counter electrode; Electrocatalytic activity

Abstract:We report the synthesis of efficient noble metal-free counter electrode materials, Co@N-doped carbon nanotubes by one-step direct pyrolysis of ZIF-67 metal-organic framework under hydrogen atmosphere. It has been demonstrated that the dye-sensitized solar cell using Co@N-doped carbon nanotubes as counter electrode exhibits the best power conversion efficiency of 8.18% than that of 7.54% using Pt counter electrode due to its excellent electrocatalytic activity towards the reduction of I-/I-3(-). The results indicate the enormous potential of Co@N-doped carbon nanotubes in commercialization of low cost DSSCs.