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个人信息Personal Information
研究员
博士生导师
硕士生导师
性别：男
毕业院校：德国马普高分子所
学位：博士
所在单位：化工学院
办公地点：大连理工大学西部校区E-226
联系方式：sunwen@dlut.edu.cn
电子邮箱：sunwen@dlut.edu.cn
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P-Doped carbons derived from cellulose as highly efficient metal-free catalysts for aerobic oxidation of benzyl alcohol in water under an air atmosphere
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论文类型：期刊论文
发表时间：2018-08-21
发表刊物：CHEMICAL COMMUNICATIONS
收录刊物：SCIE
卷号：54
期号：65
页面范围：8991-8994
ISSN号：1359-7345
摘要：P-Doped carbons, prepared by carbonizing phosphoric acid-treated cellulose, exhibit high catalytic activity in metal-free aerobic oxidation of benzyl alcohol to benzaldehyde (99.7% yield) in water under air. A high turnover frequency is obtained due to the doped P-species of C3PO, identified via experiments and DFT calculations.