柳丽芬

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教授

博士生导师

硕士生导师

主要任职:盘锦校区食品与环境学院副院长 Vice Dean School of Food and Environment Panjin Campus Dalian University of Technology

性别:女

毕业院校:大连理工大学

学位:博士

所在单位:化工海洋与生命学院

学科:环境工程. 环境科学

办公地点:环境学院 B 505

化工 海洋与生命学院  D05-201

联系方式:0427-2631799;

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Removal of aqueous Hg(II) and Cr(VI) using phytic acid doped polyaniline/cellulose acetate composite membrane

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论文类型:期刊论文

发表时间:2014-09-15

发表刊物:JOURNAL OF HAZARDOUS MATERIALS

收录刊物:SCIE、EI、PubMed、Scopus

卷号:280

页面范围:20-30

ISSN号:0304-3894

关键字:Polyaniline; Cellulose acetate; Hg(II); Cr(VI); Adsorption

摘要:Conductive composite membrane-phytic acid (PA) doped polyaniline (PANI)/cellulose acetate (CA) (PANI-PA/CA) was prepared in a simple and environmental-friendly method, in which aniline was blended with CA/PA solution and polymerized before the phase conversion. The resultant composite membranes were characterized by SEM, EDX, FTIR-ATR, BET and electrical resistance measurements. When used as adsorbent for Hg(II) and Cr(VI) ions, the prepared composite membrane exhibits excellent adsorption capability. The adsorption of Hg(II) and Cr(VI) follows a pseudo-second-order kinetic model and best fits the Langmuir isotherm model, with the maximum adsorption capacity reaching 280.11 and 94.34 mg g(-1), respectively. The heavy metal loaded composite membrane can be regenerated and reused after treatment with acid or alkali solution, making it a promising and practical adsorbent for Hg(II) and Cr(VI) removal. Tests with river water were also carried out, indicating good performance and application. (C) 2014 Elsevier B.V. All rights reserved.