论文名称:An active and coke-resistant dry reforming catalyst comprising nickel-tungsten alloy nanoparticles 论文类型:期刊论文 发表刊物:CATALYSIS COMMUNICATIONS 收录刊物:SCIE、EI、Scopus 卷号:69 页面范围:123-128 ISSN号:1566-7367 关键字:Methane; Carbon dioxide; Tungsten carbide; Nickel 摘要:Nickel catalysts catalyzing the DRM reaction have the problems of sintering and coking. Herein we proposed an idea of stabilizing nickel by Ni17W3 alloy, and alpha-WC formed during the DRM reaction participated in the CO2 activation, leading to a better coke resistance of Ni17W3/SiO2 catalyst. Due to better Ni dispersion and less coke deposition, Ni17W3/SiO2 catalyst exhibits an improved catalytic stability for the DRM reaction compared with the model Ni/SiO2 catalyst. (C) 2015 Elsevier B.V. All rights reserved. 发表时间:2015-09-05