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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工全国重点实验室主任，教育部智能材料化工前沿科学中心执行主任，大连理工大学膜科学与技术研究开发中心主任
性别：女
毕业院校：中国科学院大连化物所
学位：博士
所在单位：化工学院
学科：化学工程. 膜科学与技术. 生物医学工程
联系方式：hgaohong@dlut.edu.cn
电子邮箱：hgaohong@dlut.edu.cn
A hybrid ultrovilet detector based on polystyrene sulfate modified TiO2 nanocrystalline
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论文类型：期刊论文
发表时间：2017-08-01
发表刊物：SOLID STATE COMMUNICATIONS
卷号：262
页面范围：29-32
ISSN号：0038-1098
关键字：TiO2 nanocrystalline film; Polystyrene sulfate; Hybrid detector; Responsivity
摘要：A hybrid polystyrene sulfate (PSS) modified TiO2 nanocrystalline (NC) composite film based ultrovilet (UV) photodetector (PD) was proposed in this study. TiO2 NC film with uniform size distribution was deposited on FTO glass by doctor blading P25 TiO2 nanoparticles. Through layer-by-layer self-assembly, PSS/TiO2 composite film was prepared and it exhibits a high responsivity of 602 AW(-1), a large photo-to-dark current ratio of 193200% and a low dark current of 7 nA at only 0.1 V bias. The obtained high responsivity is almost 1-2 orders of magnitude higher than that of mostly reported TiO2 NC film based UV PDs. The reason is attributed to the injection of electrons from PSS into conduction band of TiO2 and the separation improvement of photo generated electrons and holes by the rutile/anatase junction in the TiO2 NC film. Considering the high responsive performances and facile low-cost fabrication, the proposed PSS/TiO2 composite film based UV PD shows a bright prospect in large-area UV detection application.A hybrid polystyrene sulfate (PSS) modified TiO2 nanocrystalline (NC) composite film based ultrovilet (UV) photodetector (PD) was proposed in this study. TiO2 NC film with uniform size distribution was deposited on FTO glass by doctor blading P25 TiO2 nanoparticles. Through layer-by-layer self-assembly, PSS/TiO2 composite film was prepared and it exhibits a high responsivity of 602 AW(-1), a large photo-to-dark current ratio of 193200% and a low dark current of 7 nA at only 0.1 V bias. The obtained high responsivity is almost 1-2 orders of magnitude higher than that of mostly reported TiO2 NC film based UV PDs. The reason is attributed to the injection of electrons from PSS into conduction band of TiO2 and the separation improvement of photo generated electrons and holes by the rutile/anatase junction in the TiO2 NC film. Considering the high responsive performances and facile low-cost fabrication, the proposed PSS/TiO2 composite film based UV PD shows a bright prospect in large-area UV detection application.