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NDI-TEMPO和PBI-TEMPO化合物:三重态的产生及电子自旋极化效应
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Indexed by:会议论文

Date of Publication:2017-08-21

Page Number:369-370

Key Words:EISC;自由基;四重态;时间分辨电子顺磁共振(TR-EPR)

Abstract:  自由基与荧光团相连后得到的化合物,具有潜在的光、磁性质.本工作将稳定的自由基TEMPO以刚性连接到荧光团NDI和PBI上,使二者之间有一定的距离和取向,由于自由基与荧光团的电子自旋耦合相互作用,荧光团的荧光被淬灭,并且有效地产生了三重态(EISC)[1].通过时间分辨电子顺磁共振(TR-EPR),首次观察到了NDI发色团的四重态.PBI-TEMPO的电子自旋极化(ESP)与之前报道的也完全不同[2].

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Alma Mater:Jilin University

Degree:Doctoral Degree

School/Department:School of Chemistry Engineering

Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)

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