Indexed by:会议论文
Date of Publication:2017-08-21
Page Number:530-531
Key Words:三重态光敏剂;BODIPY;敏化单线态氧;光物理光化学
Abstract: 基于BODIPY设计并合成了新型无重原子纯有机三重态光敏剂并成功用于敏化产生单线态氧,该三重态光敏剂(噻吩并BODIPY)具有高达63.7％的三重态量子产率,在敏化单线态氧上,获得了高达58％的活性氧产率.本研究同时采用DFT/TDDFT和SOS-CIS(D)计算方法,从理论上揭示了S元素的引入对BODIPY三重态量子产率的影响[1,2].该研究成果为纯有机三重态光敏剂的制备以及在敏化产生单线态氧的应用研究提供了良好的理论依据和实践经验[1-3].
Professor
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates
Gender:Male
Alma Mater:Jilin University
Degree:Doctoral Degree
School/Department:School of Chemistry Engineering
Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)
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