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通过构型约束调控萘酰亚胺衍生物的电子耦合并观察到热激活延迟荧光
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Indexed by:会议论文

Date of Publication:2017-08-21

Page Number:368-368

Key Words:热激活延迟荧光;萘酰亚胺;电子耦合;系间窜越

Abstract:  重原子(Br,I,Pt,Pd)可提高有机染料受光激发后的系间窜越能力1,但是一些无重原子的化合物也能产生三重激发态2.为了研究在无重原子存在下,通过自旋轨道耦合电荷转移和复合产生的三重态,本工作将不同的电子给体连接到萘酰亚胺荧光团上,探究了不同的旋转空间位阻对电子给体与受体间电子耦合的影响.观察到萘酰亚胺衍生物的热激活延迟荧光,通过除氧发光及寿命、变温发光及寿命和纳秒瞬态吸收等测试手段研究了该延迟发光的性质和机理3.

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Gender:Male

Alma Mater:Jilin University

Degree:Doctoral Degree

School/Department:School of Chemistry Engineering

Discipline:Organic Chemistry. Applied Chemistry. Physical Chemistry (including Chemical Physics)

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