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论文类型： 期刊论文

发表时间： 2017-09-28

发表刊物： JOURNAL OF MATERIALS RESEARCH

收录刊物： SCIE

卷号： 32

期号： 18

页面范围： 3555-3563

ISSN号： 0884-2914

摘要： Ni/Sn-xZn/Ni (x = 1, 5, 9 wt%) joints were used to investigate the effect of Zn content on interfacial reactions during reflow under a temperature gradient. Asymmetrical growth and transformation of intermetallic compounds (IMCs) occurred between the cold and hot end interfaces. Faster IMC growth at the cold end and a more prompt IMC transformation at the hot end in a lower Zn content solder joint were identified due to the more thermomigration-induced Zn and Ni atomic fluxes toward the cold end. The main diffusion species into IMC layers changed from Zn atoms at the early stage to Sn and Ni atoms at the later stage. As a result, the IMC evolution followed (Ni, Zn)(3)Sn-4 -> Ni3Sn4 in the Ni/Sn-1Zn/Ni joint, Ni5Zn21 -> tau phase -> Ni3Sn4 in the Ni/Sn-5Zn/Ni joint, and Ni5Zn21 -> tau phase in the Ni/Sn-9Zn/Ni joint along with the reflow time. A higher Zn content could effectively inhibit the dissolution of the hot-end Ni substrate and restrain the growth rate of the cold-end interfacial IMCs.