- Conjugated microporous polymer nanotubes and hydrophobic sponges
- 点击次数：
- 论文类型： 期刊论文
- 发表时间： 2014-09-15
- 发表刊物： MICROPOROUS AND MESOPOROUS MATERIALS
- 收录刊物： SCIE、EI、Scopus
- 卷号： 196
- 页面范围： 335-340
- ISSN号： 1387-1811
- 关键字： Conjugated microporous polymers; Nanotubes; Hydrophobic sponges; Porous materials; Oil-water separation
- 摘要： Novel nanotube-like conjugated microporous polymer (CMP) with a large surface area was prepared by one-step chemical synthesis via cross-coupling of 1,4-diethynylbenzene and 2,4,6-tribromophenol. Due to its unique surface hydrophobicity and porous feature, we prepared CMP nanotube-based hydrophobic sponges by filling the CMP nanotubes into melamine sponges to afford a bulk absorbent via the method similar to "ship-in-bottle". The CMP treated sponges exhibit excellent absorption capacity and recyclability for separation of organics from water. Moreover, the absorbates can be re-collected simply by squeezing the treated sponge. This work provides a simple and efficient method to prepare hydrophobic, oleophilic sponge materials, which is of technological significance for potential use, especially for oil-spill cleanups or removal of organic pollutants from water. (C) 2014 Elsevier Inc. All rights reserved.
