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个人信息Personal Information
副教授
博士生导师
硕士生导师
主要任职：associate professor
性别：男
毕业院校：清华大学
学位：博士
所在单位：化学学院
学科：有机化学
办公地点：大连理工大学化学楼121
联系方式：15140340948
电子邮箱：jinyh18@dlut.edu.cn
个人简介Personal Profile
金云鹤 博士
化学学院 副教授 博士生导师 化学学院院长助理
2009年以辽宁省高考总分第二名考入清华大学化学系化学生物学基础科学班，2013年获得理学学士学位并保送至清华大学化学系攻读博士学位，师从付华教授，2018年7月获得理学博士学位，同年就职于大连理工大学张大煜学院（现化学学院），并与大连市智能化学重点实验室主任陶胜洋教授、精细化工国家重点实验室段春迎教授展开全面合作。主要研究领域为金属-有机超分子材料在能源转化及光电有机催化方面的研究，以及绿色有机合成反应的开发。目前已在Chem. Soc. Rev., J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nat. Commun., Green Chem., Org. Lett.等高水平学术期刊上发表论文三十余篇，多次作为封面文章和热点文章被评述引用。曾获教育部国家奖学金、清华大学优秀博士毕业生、清华大学优秀博士毕业论文、清华大学“启航奖”等多项奖励奖项。
课题组常年诚聘有机合成化学及金属-有机超分子光化学方向的博士后，愿有志之士积极加入我们，共同奋斗！
课题组在轻质烷烃催化转化、功能分子及医药中间体的设计合成方面具备丰富的开发及研究经验，诚邀各类企事业单位与课题组展开合作，共创辉煌！
代表性论文：
Yun Zou, Jia Xin, Yunhe Jin* and Shengyang Tao*. Flux-Screened Copper/Electric Dual-Catalyzed Chemo- and Enantioselective Ullmann-Type C−C Coupling Reactions. Org. Lett. 2024, 26, in press.
Yongqiang Zhang,‡ Dongmin Fu,‡ Ziyang Chen, Rongqi Cui, Wenlong He, Hongyao Wang, Jiajin Chen, Yufei Chen, Shi-Jun Li, Yu Lan*, Chunying Duan, and Yunhe Jin*. Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping. Nat. Commun. 2024, 15, 8619.
link: https://doi.org/10.1038/s41467-024-53021-x
Rongqi Cui,‡ Qian Liao,‡ Yuanxia Zhao, Lifang Wang, Yongqiang Zhang, Shuyang Liu, Ziyu Gan, Yufei Chen, Yi Shi, Lei Shi, Min Li, and Yunhe Jin*. Metal and photocatalyst-free amide synthesis via decarbonylative condensation of alkynes and photoexcited nitroarenes. Org. Lett. 2024, 26, 8222−8227.
Ziyu Gan, Jiajin Chen, Han Wang, Zhiyan Xue, Ziyang Chen, Yongqiang Zhang, Lifang Wang, Hui Zi, Shuyang Liu, Lei Shi, and Yunhe Jin*. Photoinduced Phosphoniumation of Aryl Halides and Arylthianthrenium salts via an Electron Donor-Acceptor Complex. Org. Lett. 2024, 26, 7751−7756.
Ziyu Gan, Shuyang Liu, Jiajin Chen, Ziyang Chen, Yongqiang Zhang, Lifang Wang, Han Wang, Yihao Li, and Yunhe Jin*. A Modular Three-Component Approach for Site-selective Tandem Arene Thiophosphorylation. Org. Lett. 2024, 26, 7155−7160.
Jiajin Chen,‡ Ziyu Gan,‡ Yongqiang Zhang, Ziyang Chen, Shuyang Liu, Rongqi Cui, Zhiyan Xue, Haoxiang Sun, Lei Shi, Wen-Feng Jiang, and Yunhe Jin*. Iron-Catalyzed Photoredox Alcohol α‑C−H Alkylation and Tandem Intramolecular Cyclization: Facile Access to Multisubstituted 2,3-Dihydrofurans and γ‑Butyrolactones. Org. Lett. 2024, 26, 5329−5334.
Jinglan Lei, Min Li,* Qingqing Zhang, Shuyang Liu, Haifang Li, Lei Shi, Wen-Feng Jiang, Chunying Duan, and Yunhe Jin*. Visible-Light-Induced Radical Cascade Cross-Coupling via C(sp3)−H Activation and C−N/N−O Cleavage: Feasible Access to Methylenebisamide Derivatives. Org. Lett., 2023, 25, 2300−2305.
Qingqing Zhang, Yunhe Jin,* Lin Ma, Yongqiang Zhang, Changgong Meng, Chunying Duan,* Chromophore-inspired design of pyridinium-based metal-organic polymers for dual photoredox catalysis. [Hot paper & back cover] Angew. Chem. Int. Ed., 2022, 61, e202204918.
Qingqing Zhang, Shuyang Liu, Jinglan Lei, Changgong Meng, Chunying Duan, Yunhe Jin*. Iron-catalyzed photoredox functionalization of methane and heavier gaseous alkanes: scope, kinetics, and computational studies. Org. Lett. 2022, 24, 1901−1906.
Xinyao Wang, Qingqing Zhang, Shuyang Liu, Min Li*, Haifang Li*, Chunying Duan, Yunhe Jin*. Visible light-induced metal-free benzylation of quinones via cross dehydrogenation coupling reaction. Chin. J. Org. Chem. 2022, 42, 1443−1452.
Yunhe Jin,*† Lifang Wang†, Qingqing Zhang, Yongqiang Zhang, Qian Liao, Chunying Duan*. Photo-induced direct alkynylation of methane and other light alkanes by iron catalysis. [Hot article] Green Chem., 2021, 23, 9406−9411.
Yongqiang Zhang,† Yunhe Jin,*† Lifang Wang, Qingqing Zhang, Changgong Meng, Chunying Duan*. Selective C(sp3)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H2O2 as sustainable oxidants. [Hot article] Green Chem. 2021, 23, 6926−6930.
Yunhe Jin,*† Qingqing Zhang,† Lifang Wang, Xinyao Wang, Changgong Meng, Chunying Duan*. Convenient C(sp3)–H bond functionalisation of light alkanes and other compounds by iron photocatalysis. [Hot article] Green Chem. 2021, 23, 6984−6989.
Yunhe Jin, Qingqing Zhang, Yongqiang Zhang, Chunying Duan*. Electron transfer in the confined environments of metal–organic coordination supramolecular systems. Chem. Soc. Rev. 2020, 49, 5561−5600.
Yunhe Jin, Lunyu Ou, Haijun Yang, Hua Fu*. Visible light-mediated aerobic oxidation of N-alkylpyridinium salts under organic photocatalysis. J. Am. Chem. Soc. 2017, 139, 14237−14243.
Yunhe Jin, Hua Fu*. Visible-light photoredox decarboxylative couplings. [Highly cited paper & inside cover] Asian J. Org. Chem. 2017, 6, 368-385.
Yunhe Jin, Haijun Yang, Hua Fu*. Thiophenol-catalyzed visible-light photoredox decarboxylative couplings of N-(acetoxy)phthalimides. Org. Lett. 2016, 18, 6400-6403.
Yunhe Jin, Haijun Yang, Hua Fu*. An N-(acetoxy)phthalimide motif as a visible-light pro-photosensitizer in photoredox decarboxylative arylthiation. Chem. Commun. 2016, 52, 12909-12912.
Yunhe Jin, Min Jiang, Hui Wang, Hua Fu*. Installing amino acids and peptides on N-heterocycles under visible-light assistance. Sci. Rep. 2016, 6, 20068.
代表性专利：
金云鹤、张晴晴、段春迎，一种基于铁/光联合催化获得甲烷功能化产物的制备方法，ZL 2021 1 1082684.0，中国