纳米和微米ZSM-5分子筛在焦化苯乙基化反应体系中稳定性比较

Release Time:2023-05-13  Hits:

Date of Publication: 2022-10-06

Journal: 石油学报 石油加工

Issue: 1

Page Number: 46-50

ISSN: 1001-8719

Abstract: The ethylation of coking benzene over ZSM-5 zeolites with different crystal size was investigated. The results showed that the difference in catalyst stability of nano-sized and micro-sized ZSM-5 zeolites in ethylation depended strongly on the type of ethylation agent. When ethanol was used as the ethylating agent, ZSM-5-m-25 prepared from micro-sized ZSM-5 zeolite exhibited better catalysis stability than ZSM-5-n-25 prepared from nano-sized ZSM-5 zeolite. When ethyene was used as the ethylating agent, ZSM-5-n-25 showed better catalyst stability than ZSM-5-m-25.

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