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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：大连理工大学
学位：硕士
所在单位：化工学院
学科：药物工程. 精细化工. 药物化学
办公地点：大连理工大学西部校区化工实验楼G段311
联系方式：mengqw@dlut.edu.cn
电子邮箱：mengqw@dlut.edu.cn
扫描关注
Bifunctional metal-free photo-organocatalysts for enantioselective aerobic oxidation of beta-dicarbonyl compounds
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论文类型：期刊论文
发表时间：2018-07-05
发表刊物：TETRAHEDRON
收录刊物：SCIE
卷号：74
期号：27
页面范围：3624-3633
ISSN号：0040-4020
关键字：Photo-organocatalyst; Bifunctional; Visible-light; Metal-free; Oxidation
摘要：A series of bifunctional metal-free photo-organocatalysts have been developed by grafting the photo-sensitizer to cinchona-derived phase-transfer catalysts. Using air as a green oxidant and visible light as the driving force, these catalysts are applied to the oxidation of a range of beta-dicarbonyl compounds in good yields (up to 97%) and enantioselectivities (up to 93:7 er). (C) 2018 Elsevier Ltd. All rights reserved.