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    王立达

    • 副教授       硕士生导师
    • 性别:男
    • 毕业院校:大连理工大学
    • 学位:博士
    • 所在单位:化工学院
    • 学科:化学工程
    • 办公地点:大连理工大学西部校区化工综合楼A506
    • 电子邮箱:ldwang@dlut.edu.cn

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    Tuning the functionalization degree of graphene: Determining critical conditions for inhibiting the corrosion promotion activity of graphene/epoxy nanocomposite coatings

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    论文类型:期刊论文

    发表时间:2019-04-01

    发表刊物:MATERIALS LETTERS

    收录刊物:SCIE、EI

    卷号:240

    页面范围:262-266

    ISSN号:0167-577X

    关键字:Graphene; Functionalization; Composite materials; Corrosion; LEIS

    摘要:Graphene functionalization helps to improve the barrier property of graphene-reinforced coatings, however, it may also increase the electrical conductivity of coatings and result in galvanic corrosion between coating and metal. To demonstrate that fine-tuned functionalization of graphene is vital for its applications in metal protection, reduced graphene oxide (rGO) with various functionalization degree was precisely prepared. Compared with pristine rGO, rGO with a low functionalization degree possesses an enhanced corrosion promotion activity (CPA), and rGO with a high functionalization degree exhibits an inhibited CPA. Critical functionalization degree for inhibiting the CPA of rGO/epoxy nanocomposite coatings was determined. (C) 2019 Elsevier B.V. All rights reserved.