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Indexed by:期刊论文

Date of Publication:2016-10-19

Journal:ACS APPLIED MATERIALS & INTERFACES

Included Journals:SCIE、EI、PubMed

Volume:8

Issue:41

Page Number:27843-27849

ISSN No.:1944-8244

Key Words:lithium-ion batteries; anodes; nanoflake network; biomass; manganese oxide

Abstract:Numerous natural resources have a highly interconnected network with :developed,porous structure; so enabling directional and fast-matrix transport. Such structures are appealing for the design 'Of efficient anode materials for lithium-ion batteries, although they can be challenging to prepare. Inspired by nature a novel synthesis route from biomass is proposed by using readily available auricularia as retractable suppOrt and carbon coating precursor to soak up "metal salt solution. Using the swelling properties.of the auricularia with the complexation of metal ions; a nitrogen-containing MriO@C nannflake network has been, easily synthesized with fast electrochemical reaction dynamies and'a superior lithium storage performance. A subsequent carbonization results in the it. situ synthesis of MnO nanoparticles throughout the porous carbon flake network. When evaluated as an anode material for lithium-ion batteries, an excellent reversible capacity is achieved of 868 mA. h g(-1) at 0.2 A g(-1) over 300 cycles and 668 mA h g(-1) at 1 A g(-1) over 500 cycles, indicating a high tolerance to the volume expansion. The approach investigated opens up new avenues for the design of high performance electrodes with highly cross-linked nanoflake structures, which may have great application prospects.