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论文类型： 期刊论文

发表时间： 2017-09-01

发表刊物： DYES AND PIGMENTS

收录刊物： SCIE、EI、Scopus

卷号： 144

页面范围： 184-189

ISSN号： 0143-7208

关键字： Perylene diimides; Bisalkynyl compound; Organic functional dyes; Efficient synthesis; High electron mobility

摘要： A series of aryl-bisalkynyl bridged perylene diimides derivatives were efficiently synthesized through the Sonogashira-type coupling reaction, and their photophysical, electrochemical and electron-transporting properties were investigated in detail. With the introduction of aryl-bisallcynyl groups, their absorption spectra exhibit extra strong absorption in the short wavelength region and therefore realizing broad wavelength range from 300 to 700 nm, which can overcome the weakness of narrow half: peak width of N,N'-bis(1-ethylpropyl)perylene-3,4,9,10-tetracarboxylic acid bisimides (PDI). The lowest unoccupied molecular orbital (LUMO) levels (about -4.00 eV) are lower than that of the prototype PDI, which make them potential for excellent electron-transporting materials. As a result, the improved electron mobilities of 10(-4) cm(2) s(-1), which is three orders of magnitude higher than that of PDI, were obtained in space charge limited current (SCLC) devices. (C) 2017 Published by Elsevier Ltd.