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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：男
毕业院校：浙江大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工. 有机化学
办公地点：大连市甘井子区凌工路2号
大连理工大学西部校区E座406室
联系方式：15040537236 zhangtiexin@dlut.edu.cn
电子邮箱：zhangtiexin@dlut.edu.cn
Rhodium-Catalyzed Highly Regioselective and Stereoselective Intermolecular Hydrosilylation of Internal Ynamides under Mild Conditions.
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论文类型：期刊论文
发表时间：2018-01-01
发表刊物：The Journal of organic chemistry
收录刊物：PubMed、SCIE
卷号：83
期号：11
页面范围：6210-6216
ISSN号：1520-6904
摘要：A rhodium-catalyzed highly regio- and stereoselective intermolecular hydrosilylation of internal ynamides has been developed. With the neutral rhodium complex [Rh(CO)2Cl]2 as a catalyst and the bulky silanes as reactants, various ynamides underwent hydrosilylation smoothly at room temperature with an excellent beta-regioselectivity and anti-stereoselectivity. The synthetically versatile beta-silyl ( Z)-enamide products could be further transformed to diverse useful building blocks. Several possible mechanisms are proposed to rationalize this unique formal trans-addition-type selectivity.
上一条：Thiophene insertion for continuous modulation of the photoelectronic properties of triphenylamine-based metal-organic frameworks for photocatalytic sulfonylation-cyclisation of activated alkenes
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