个人信息Personal Information
副教授
博士生导师
硕士生导师
性别:男
毕业院校:浙江大学
学位:博士
所在单位:化工学院
学科:应用化学. 精细化工. 有机化学
办公地点:大连市甘井子区凌工路2号
大连理工大学西部校区E座406室
联系方式:15040537236 zhangtiexin@dlut.edu.cn
电子邮箱:zhangtiexin@dlut.edu.cn
Modulating photoelectronic performance of metal-organic frameworks for premium photocatalysis
点击次数:
论文类型:期刊论文
发表时间:2019-02-01
发表刊物:COORDINATION CHEMISTRY REVIEWS
收录刊物:SCIE、Scopus
卷号:380
页面范围:201-229
ISSN号:0010-8545
摘要:As inorganic-organic hybrid materials, metal-organic frameworks (MOFs) exhibit the combined advantages of inorganic semiconductor-type photocatalysts and organic/organometallic molecular photocatalysts in the field of solar energy conversion. The excited states, charge separations, and charge mobilities of MOFs remarkably influence the results of MOF-based photocatalytic systems, which reflect varying degrees of characteristics of inorganic semiconductors and organic/organometallic dyes. In this review, we aim to examine how the aforementioned photoelectronic performances affect each step of the photocatalytic processes based on the recent advances of energy catalysis and organic transformations by using MOFs, and attempt to find new clues for modulating the photoelectronic properties of MOF-based catalytic systems to achieve premium photocatalytic efficiencies and selectivities. (C) 2018 Elsevier B.V. All rights reserved.
上一条:Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions
下一条:Thiophene insertion for continuous modulation of the photoelectronic properties of triphenylamine-based metal-organic frameworks for photocatalytic sulfonylation-cyclisation of activated alkenes