张铁欣

个人信息Personal Information

副教授

博士生导师

硕士生导师

性别:男

毕业院校:浙江大学

学位:博士

所在单位:化工学院

学科:应用化学. 精细化工. 有机化学

办公地点:大连市甘井子区凌工路2号
大连理工大学西部校区E座406室

联系方式:15040537236 zhangtiexin@dlut.edu.cn

电子邮箱:zhangtiexin@dlut.edu.cn

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Modulating photoelectronic performance of metal-organic frameworks for premium photocatalysis

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论文类型:期刊论文

发表时间:2019-02-01

发表刊物:COORDINATION CHEMISTRY REVIEWS

收录刊物:SCIE、Scopus

卷号:380

页面范围:201-229

ISSN号:0010-8545

摘要:As inorganic-organic hybrid materials, metal-organic frameworks (MOFs) exhibit the combined advantages of inorganic semiconductor-type photocatalysts and organic/organometallic molecular photocatalysts in the field of solar energy conversion. The excited states, charge separations, and charge mobilities of MOFs remarkably influence the results of MOF-based photocatalytic systems, which reflect varying degrees of characteristics of inorganic semiconductors and organic/organometallic dyes. In this review, we aim to examine how the aforementioned photoelectronic performances affect each step of the photocatalytic processes based on the recent advances of energy catalysis and organic transformations by using MOFs, and attempt to find new clues for modulating the photoelectronic properties of MOF-based catalytic systems to achieve premium photocatalytic efficiencies and selectivities. (C) 2018 Elsevier B.V. All rights reserved.