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论文类型：期刊论文

发表时间：2016-09-01

发表刊物：SENSORS AND ACTUATORS B-CHEMICAL

收录刊物：SCIE、EI、Scopus

卷号：232

期号：232

页面范围：545-556

ISSN号：0925-4005

关键字：SnO2 hollow nanosphere; Metallic silver; Methoxy propanol; Catalytic effect; Gas sensing mechanism

摘要：Ag-decorated SnO2 hollow spheres with different mass ratios were synthesized through a two-step synthesis route. The morphology of as-prepared materials was characterized via FESEM and TEM microscopes, and the results proved the rough and porous spherical structures. The EDX and XPS patterns verified the elementary composition, especially for Ag/SnO2, the standard peaks of Ag were obviously observed. The N-2 isotherm of SnO2 hollow spheres belongs to a type-IV isotherm with a large type H3 hysteresis loop. The pore size distribution covered a range of 35-80 nm and the sample showed a high BET surface area of 31.91 m(2)/g. During the systematic examinations of gas sensing performance, 5 wt% Ag/SnO2 showed superior properties, including the ultrahigh response of over one hundred to methoxy propanol within a wide concentration range and the excellent selectivity for detecting methoxy propanol among other gases. Moreover, the synthesis mechanism and gas sensing mechanism were discussed, which indicated that both the morphology of SnO2 hollow spheres and the catalytic effect of Ag nanoparticles played important roles on the gas sensing properties, and could be used for the further design of gas sensor utilizing other oxide semiconductors. (C) 2016 Elsevier B.V. All rights reserved.