常钧

个人信息Personal Information

教授

博士生导师

硕士生导师

性别:男

毕业院校:武汉理工大学

学位:博士

所在单位:土木工程系

学科:材料学. 结构工程

联系方式:mlchang@dlut.edu.cn

电子邮箱:mlchang@dlut.edu.cn

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Microstructure changes of waste hydrated cement paste induced by accelerated carbonation

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论文类型:期刊论文

发表时间:2015-02-01

发表刊物:CONSTRUCTION AND BUILDING MATERIALS

收录刊物:SCIE

卷号:76

页面范围:360-365

ISSN号:0950-0618

关键字:Waste hydrated cement paste; Accelerated carbonation; Competitive carbonation; QXRD; TG

摘要:From the perspective of effective utilization of resources and environmental preservation, accelerated carbonation of waste cement paste is a promising and environmentally beneficial application. Greenhouse gas CO2 can be captured, waste hydrated cement can be reused, and building materials with excellent performance can be produced. In this study, samples were exposed to high CO2 concentration (99.9 wt%, 0.2 MPa) for accelerated carbonation. The compacts with water/solid ratio of 0.15 absorbed 19.8 wt% CO2 after carbonated for 2 h, and the compressive strength was 28.6 MPa. The total pore volume decreased from 0.41 cm(3)/g to 0.26 cm(3)/g due to the precipitation of calcium carbonate and silica gel. Rietveld refinement quantitative phase analysis and TG analysis showed calcium carbonate are mainly from Ca(OH)(2) and C-S-H, accounting for about 70-80% of the total calcium carbonate. Ca(OH)(2) has superiority in the early carbonation period, and the carbonated compacts has a relative higher "compressive strength-to-CO2 uptake" value, corresponding. When the carbonation degree of C-S-H and other carbonation phase exceed Ca(OH)(2) in the later stage, the compressive strength has a slower gain tendency. (C) 2014 Elsevier Ltd. All rights reserved.