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One-Nanometer-Precision Control of Al2O3 Nanoshells through a Solution-Based Synthesis Route

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2014-11-17

Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals: Scopus、EI、SCIE

Volume: 53

Issue: 47

Page Number: 12776-12780

ISSN: 1433-7851

Key Words: Al2O3 coating; core-shell structure; layer thickness; lithium-ion batteries

Abstract: Forming uniform metal oxide nanocoatings is a well-known challenge in the construction of core-shell type nano-materials. Herein, by using buffer solution as a specific reaction medium, we demonstrate the possibility to grow thin nano-shells of metal oxides, typically Al2O3, on different kinds of core materials, forming a uniform surface-coating layer with thicknesses achieving one nanometer precision. The application of this methodology for the surface modification of LiCoO2 shows that a thin nanoshell of Al2O3 can be readily tuned on the surface for an optimized battery performance.

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