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Indexed by:期刊论文

Date of Publication:2012-03-16

Journal:JOURNAL OF ORGANIC CHEMISTRY

Included Journals:PubMed、SCIE、EI、Scopus

Volume:77

Issue:6

Page Number:2942-2946

ISSN No.:0022-3263

Abstract:With the direct use of allylic alcohols as allylating agents, the Friedel Crafts-type allylic alkylation of nitrogen-containing aromatic compounds catalyzed by a [Mo3S4Pd(eta(3)-allyl)] cluster is achieved. With a 3 mol % catalyst loading in acetonitrile at re lux or 60 degrees C, a variety of N,N-dialkylanilines and indoles reacted smoothly with allylic alcohols to afford the Friedel-Crafts-type allylation products in good to excellent yields with high levels of regioselectivity.