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P-Doped carbons derived from cellulose as highly efficient metal-free catalysts for aerobic oxidation of benzyl alcohol in water under an air atmosphere

Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2018-08-21

Journal: CHEMICAL COMMUNICATIONS

Included Journals: SCIE

Volume: 54

Issue: 65

Page Number: 8991-8994

ISSN: 1359-7345

Abstract: P-Doped carbons, prepared by carbonizing phosphoric acid-treated cellulose, exhibit high catalytic activity in metal-free aerobic oxidation of benzyl alcohol to benzaldehyde (99.7% yield) in water under air. A high turnover frequency is obtained due to the doped P-species of C3PO, identified via experiments and DFT calculations.

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