研究概述

当今世界正在经历前所未有之变革，而能源与环境问题已成为一个国家和一个社会持续性发展所面临的首要问题。本团队的学术研究目标是建立一个世界级的先进微纳米表界面构建与过程强化的研究平台，从微纳米技术与表界面科学的角度出发为解决环境与能源方面的挑战提出全新的策略。依托于大连理工大学微纳米技术及系统重点实验室资源，未来团队拟开展的研究课题将围绕功能微纳米表界面构建与过程强化的研究方向，通过结合微纳加工、功能高分子、界面力学以及表面工程的研究背景来构筑跨尺度多功能微纳米表界面。具体的研究课题包含：一. 液体自运输微纳米表界面的构建与应用; 二. 先进传热微纳米表界面的构建与应用; 三. 新型拒液及耐污微纳米表界面的构建与应用；四. 超润滑微纳米表界面的构建与应用。这些课题面向解决的全球性挑战将涉及大气水收集、热能利用、海洋防污、及防冰除冰等基础科学问题。希望可以设计并构建适用于实际工业场景的多功能特种微纳米表界面, 从中揭示表界面过程的新现象，提出表界面调控的新理论，最终将研究成果应用于航空航天、 轨道交通、船舶、新能源等国家重大需求及国际前沿的研究领域。

团队研究方向为功能表界面构建与过程强化。研究领域主要涉及表面工程、功能高分子、界面力学、以及微纳加工，具体的研究内容有智能自调节材料、新型纳米催化复合材料、拒液及耐污表面、防冰涂层、界面超润滑、液体自运输、滴装冷凝以及大气水收集等。面向解决的全球性问题包括: (1)水资源匮乏; (2)能源利用; (3)化学生物污染; (4)结冰危害。

研究经验

多功能表面

智能聚合物

超分子化学

微流体技术

论文成果

Prior to DUT

19. Sarma, J.; Zhang, L.; Guo, Z.; Dai, X. Sustainable icephobicity on durable quasi-liquid surface. Chem. Eng. J. 2021. 

18. Pu, X.-Q.; Ju, X.-J.; Zhang, L.; Cai, Q.-W.; Liu, Y.-Q.; Peng, H.-Y.; Xie, R.; Wang, W.; Liu, Z.; Chu, L.-Y. Novel Multifunctional Stimuli-Responsive Nanoparticles for Synergetic Chemo−Photothermal Therapy of Tumors. ACS Appl. Mater. Interfaces 2021.

17. Chen, Z.-H.; Liu, Z.; Zhang, L.; Cai, Q.-W.; Hu, J.-Q.; Wang, W.; Ju, X.-J; Xie, R.; Chu, L.-Y. Functional Graphene Oxide Nanosheets Modified with Cyclodextrins for Removal of Bisphenol A from Water. Chin. J. Chem. Eng. 2021.

16. Guo, Z.; Zhang, L.; Monga, D.; Stone, H.A.; Dai, X. Hydrophilic Slippery Surface Enabled Coarsening Effect for Rapid Water Harvesting. Cell Rep. Phys. Sci. 2021, 2, 100387. [Featured in ScienceDaily, UTD News, Phys.org, AAAS, and more]

15. Zhang, L.; Guo, Z.; Sarma, J.; Zhao, W.; Dai, X. Gradient Quasi-Liquid Surface Enabled Self-Propulsion of Highly Wetting Liquids. Adv. Funct. Mater. 2021, 2008614. [Featured in Advanced Sci News]

14. Zhang, L.; Guo, Z.; Sarma, J.; Dai, X. Passive Removal of Highly Wetting Liquids and Ice on Quasi-Liquid Surfaces. ACS Appl. Mater. Interfaces 2020, 12, 20084. [Featured in NanoTrac Technologies]

13. Zhang, L.; Liu, Z.; Liu, L.-Y.; Pan, J.-L.; Luo, F.; Yang, C.; Xie, R.; Ju, X.-J.; Wang, W.; Chu, L.-Y. Nanostructured Thermoresponsive Surfaces Engineered via Stable Immobilization of Smart Nanogels with Assistance of Polydopamine. ACS Appl. Mater. Interfaces 2018, 10, 44092.

12. Xie, R.; Luo, F.; Zhang, L.; Guo, S. F.; Liu, Z.; Ju, X. J.; Wang, W.; Chu, L. Y. A Novel Thermoresponsive Catalytic Membrane with Multiscale Pores Prepared via Vapor‐Induced Phase Separation. small 2018, 14, 1703650.

11. Yan, P.-J.; He, F.; Wang, W.; Zhang, S.-Y.; Zhang, L.; Li, M.; Liu, Z.; Ju, X.-J.; Xie, R.; Chu, L.-Y. Novel Membrane Detector Based on Smart Nanogels for Ultrasensitive Detection of Trace Threat Substances. ACS Appl. Mater. Interfaces 2018, 10, 36425.

10. Wang, Y.; Liu, Z.; Peng, H. Y.; He, F.; Zhang, L.; Faraj, Y.; Wang, W.; Ju, X. J.; Xie, R.; Chu, L. Y. A Simple Device Based on Smart Hollow Microgels for Facile Detection of Trace Lead (II) Ions. ChemPhysChem 2018, 19, 2025.

9. Wu W.; Zhu H.C.; Xie R.; Zhang L.; Luo F.; Ju X.J.; Wang W.; Liu Z.; Chu L.Y. Effect of Size Ratio of Smart Microgels Gates to Membrane Pores on the Responsibility of Smart Membranes. Chem. Ind. & Eng. Pro. 2018, 37, 223.

8. Deng, K.; Liu, Z.; Hu, J.; Liu, W.; Zhang, L.; Xie, R.; Ju, X.; Wang, W.; Chu, L. Composite bilayer films with organic compound-triggered bending properties. Chin. J. Chem. Eng. 2018.

7. Zhang, L.; Liu, Z.; Wang, Y.; Xie, R.; Ju, X.-J.; Wang, W.; Lin, L.-G.; Chu, L.-Y. Facile immobilization of Ag nanoparticles on microchannel walls in microreactors for catalytic applications. Chem. Eng. J. 2017, 309, 691.

6. Zhang, L.; Liu, Z.; Liu, L.-Y.; Ju, X.-J.; Wang, W.; Xie, R.; Chu, L.-Y. Novel smart microreactors equipped with responsive catalytic nanoparticles on microchannels. ACS Appl. Mater. Interfaces 2017, 9, 33137.

5. Yang, C.; Liu, Z.; Chen, C.; Shi, K.; Zhang, L.; Ju, X.-J.; Wang, W.; Xie, R.; Chu, L.-Y. Reduced graphene oxide-containing smart hydrogels with excellent electro-response and mechanical properties for soft actuators. ACS Appl. Mater. Interfaces 2017, 9, 15758.

4. Wei, Y. Y.; Liu, Z.; Luo, F.; Zhang, L.; Wang, W.; Ju, X. J.; Xie, R.; Chu, L. Y. A Novel Poly (N‐Isopropylacrylamide‐co‐acryloylamidobenzo‐12‐crown‐4) Microgel with Rapid Stimuli‐Responsiveness for Molecule‐Specific Adsorption of γ‐Cyclodextrin. Macromol. Chem. Phys. 2017, 218, 1700216.

3. Yan, S.; Wan, L. Y.; Ju, X. J.; Wu, J. F.; Zhang, L.; Li, M.; Liu, Z.; Wang, W.; Xie, R.; Chu, L. Y. K⁺-Responsive Block Copolymer Micelles for Targeted Intracellular Drug Delivery. Macromol. Biosci. 2017, 17, 1700143.

2. Zhang, L.; Wang, W.; Ju, X.-J.; Xie, R.; Liu, Z.; Chu, L.-Y. Fabrication of glass-based microfluidic devices with dry film photoresists as pattern transfer masks for wet etching. RSC Adv. 2015, 5, 5638.

1. Mou, C.-L.; Ju, X.-J.; Zhang, L.; Xie, R.; Wang, W.; Deng, N.-N.; Wei, J.; Chen, Q.; Chu, L.-Y. Monodisperse and fast-responsive poly (N-isopropylacrylamide) microgels with open-celled porous structure. Langmuir 2014, 30, 1455.

授权专利

7. Zhang L., Sarma J., Guo Z.Q., Dai X.M. "A Semiliquid Surface with Liquid and Solid Repellence". US Patent, PCT. 17/615,393. 2021.11.30.

6. 谢锐, 郭石菲, 褚良银, 骆枫, 张磊, 刘壮, 巨晓洁, 汪伟. “聚醚砜温敏催化膜及其制备方法与应用”. 中国发明专利ZL201810082547.9, 专利申请日2018.1.29, 授权时间2021.3.23.

5. 张磊, 褚良银, 刘壮, 谢锐, 巨晓洁, 汪伟, 刘露月. “一种温度响应型智能细胞培养容器的制作方法”. 中国发明专利ZL201710349645.X, 专利申请日2017.5.17, 授权时间2020.8.18.

4. 张磊, 褚良银, 刘壮, 谢锐, 巨晓洁, 汪伟, 刘露月, 杨超. “一种基于多巴胺的自聚合反应制备温度响应型表面的方法”. 中国发明专利ZL201710349054.2, 专利申请日2017.5.17, 授权时间2020.3.10.

3. 张磊, 褚良银, 刘壮, 谢锐, 巨晓洁, 汪伟, 刘露月, 骆枫. “一种温度响应型复合开关膜的制作方法”. 中国发明专利ZL201710348441.4, 专利申请日2017.5.17, 授权时间2020.8.21.

2. 张磊, 褚良银, 刘壮, 谢锐, 巨晓洁, 汪伟. “一种在微反应器通道壁面固定金属纳米催化剂的方法”. 中国发明专利ZL201610321271.6, 专利申请日2016.5.16, 授权时间2018.3.2.

1. 张磊, 褚良银, 汪伟, 谢锐, 巨晓洁, 刘壮. “以感光干膜为抗腐蚀掩膜制作玻璃微流体装置的方法”. 中国发明专利 ZL201410416124.8, 专利申请日2014.8.21, 授权时间2015.10.7. 

会议报告

14. Zhang, L.; Guo, Z.Q.; Sarma, J.; Dai, X.M. Multifunctional Semi-Liquid Surfaces with Durable Liquid Repellency [C]. 2019 MRS Fall Meeting & Exhibit, December 1-6, 2019, Boston, USA.

13. Zhang, L.; Guo, Z.Q.; Sarma, J.; Dai, X.M. Nanoscale Semi-Liquid Coating with Durable Liquid Repellency Even to Highly-Wetting Fluids [C]. IMECE2019, November 11-14, 2019, Salt Lake City, USA.

12. Guo, Z.Q.; Zhang, L.; Dai, X.M. Meniscus-Mediated Spontaneous Droplet Coalescence for Condensation [C]. IMECE2019, November 11-14, 2019, Salt Lake City, USA.

11. Pu, X.Q.; Ju, X.J.; Zhang, L.; Peng, H.Y.; Liu, Z.; Wang, W.; Xie, R.; Chu, L.Y. Tumor-Targeted Responsive Nanocarriers for Combined Photothermo Therapy and Controlled Drug Release [C]. The 257th ACS National Meeting & Exposition. March 31-April 4, 2019, Orlando, USA.

10. Zhang, L.; Liu, Z.; Liu, L.Y., Ju, X.J.; Wang, W.; Xie, R.; Chu, L.Y. Smart Thermo-Responsive Nanocatalysts for Self-Regulation of High Exothermic Reactions [C]. The 253rd ACS National Meeting, April 2-6, 2017, San Francisco, USA.

9. Wang, Y.; Liu, Z.; Peng, H.Y.; Zhang, L.; Wang, W.; Ju, X.J.; Xie, R.; Chu, L.Y. Smart Microgels as Functional Valves for Detection of Pb2+ [C]. The 253rd ACS National Meeting, April 2-6, 2017, San Francisco, USA.

8. Yang, C.; Liu, Z.; Chen, C.; Shi, K.; Zhang, L.; Ju, X.J.; Wang, W.; Xie, R.; Chu, L.Y. Reduced Graphene Oxide-Containing Smart Hydrogels with Excellent Electro-Response and Mechanical Property for Soft Actuators [C]. The 17th Congress of the Asian-Pacific Confederation of Chemical Engineering (APCChE 2017), August 23-27, 2017, Hong Kong, China.

7. Zhang, L. Environment Stimuli-Responsive Nanointerface [C]. The 1st PhD Academic Salon of Frontier Interdisciplinary at Sichuan University. Nov 18, 2016, Chengdu, China. (Invited)

6. Zhang, L.; Liu, Z.; Wang, Y.; Xie, R.; Ju, X.J., Wang, W.; Lin, L.G.; Chu, L.Y. Facile On-wall Immobilization of Ag Nanoparticles in Microreactors for Catalytic Applications [C]. The 14th International Microreaction Technology Conference (IMRET14), September 12-14, 2016, Beijing, China.

5. Liu, Z.; Zhang, L.; Ju, X.J.; Xie, R.; Wang, W.; Chu, L.Y. Smart Responsive Catalytic Nanoparticles for Chemical Self-Regulation [C]. The 9th Chinese Society of Particuology Symposium on Particle Technology Across Taiwan Strait, August 12-14, 2016, Chengdu, China.

4. Zhang, L. Thermo-Responsive Surfaces and Its Potential Bio-applications [C]. The 5th Symposium on Frontier Interdisciplinary of Biological Materials at Sichuan University, June 13, 2016, Chengdu, China. (Invited)

3. Liu, Z.; Zhang, L.; Wang, W.; Xie, R.; Ju, X.J.; Chu, L.Y. A Smart Microreactor Equipped with Responsive Catalytic Nanoparticles on Microchannels [C]. The 8th International Symposium on Microchemistry and Microsystems (ISMM 2016), May 30-June 1, 2016, Hong Kong, China.

2. Zhang, L.; Liu, Z.; Wang, W.; Xie, R.; Ju, X.J., Chu, L.Y. Facile On-wall Immobilization of Ag Nanoparticles in Microchannel Reactors for Catalytic Applications [C]. The 8th International Symposium on Microchemistry and Microsystems (ISMM 2016), May 30-June 1, 2016, Hong Kong, China.

1. Zhang, L.; Wang, W.; Ju, X.J.; Xie, R.; Liu, Z.; Chu, L.Y. Fabrication of Glass-based Microfluidic Devices with Dry Film Photoresists as Pattern Transfer Masks for Wet Etching [C]. 2015 AIChE Annual Meeting, November 8-13, 2015, Salt Lake City, USA.