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Indexed by:期刊论文

Date of Publication:2017-07-26

Journal:CHEMISTRY-A EUROPEAN JOURNAL

Included Journals:SCIE、EI、PubMed、Scopus

Volume:23

Issue:42

Page Number:10034-10037

ISSN No.:0947-6539

Key Words:Hofmann-type; iron; polymers; spin-crossover; two-step

Abstract:An unprecedented two-step spin-crossover behavior with the sequence of gamma(HS)=1 <->gamma(HS)=3/4 <->gamma(HS)=1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)(2){Ag(CN)(2)}(2)] (isoq=isoquinoline), which resulted from three crystallographically inequivalent Fe-II sites with distinct transition temperatures.