Release Time:2019-03-12  Hits:

Indexed by: Journal Article

Date of Publication: 2017-07-26

Journal: CHEMISTRY-A EUROPEAN JOURNAL

Included Journals: Scopus、PubMed、EI、SCIE

Volume: 23

Issue: 42

Page Number: 10034-10037

ISSN: 0947-6539

Key Words: Hofmann-type; iron; polymers; spin-crossover; two-step

Abstract: An unprecedented two-step spin-crossover behavior with the sequence of gamma(HS)=1 <->gamma(HS)=3/4 <->gamma(HS)=1/4 was observed in two-dimensional Hofmann type coordination polymer [Fe(isoq)(2){Ag(CN)(2)}(2)] (isoq=isoquinoline), which resulted from three crystallographically inequivalent Fe-II sites with distinct transition temperatures.