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Indexed by:期刊论文

Date of Publication:2016-04-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE

Volume:66

Page Number:55-58

ISSN No.:1387-7003

Key Words:Cyano-bridged; Single chain magnet; Spin-glass

Abstract:A cyano-bridged ferromagnetic {(Fe2FeII)-Fe-III} alternating chain {[Fe-III(pzTp)(CN)(3)](2)[Fe-II(imidazole)(H2O)])center dot 3H(2)O (1) (pzTp = tetrakis(pyrazolyl)borate) was synthesized via rational design. Crystal structure analysis studies demonstrated that complex 1 had a one-dimensional double zigzagging chain-like structure. Magnetic measurements showed that ferromagnetic interactions dominate in 1 and the AC magnetic susceptibility revealed two limit regimes in accordance with the single chain magnet and spin-glass behavior. (C) 2016 Elsevier B.V. All rights reserved.