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Indexed by:Journal Papers

Date of Publication:2015-07-01

Journal:INORGANIC CHEMISTRY COMMUNICATIONS

Included Journals:SCIE、Scopus

Volume:57

Page Number:33-35

ISSN No.:1387-7003

Key Words:Self-assembly; Cyanide; Hexanuclear; Ferromagnetic

Abstract:Two hexanuclear complexes of formula [Fe-III(Tp*)(CN)(3)](4)[Fe-II(tptz)](2) (1), [Fe-III(Tp*)(CN)(3)](4)[Co-II(tptz)](2) (2) [Tp* = hydridotris(3,5-dimethylpyrazolyl)borate, tptz = (2,4,6-tris-(2-pyridyl)1,3,5-triazine] have been synthesized via directional assembly of metallocyanate precursor and metal cationic ions. The magnetic properties characterization indicate that ferromagnetic interactions dominate in the two complexes, resulting in a spin ground state of S = 5 and S = 6, respectively. (C) 2015 Elsevier B.V. All rights reserved.