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Indexed by:期刊论文

Date of Publication:2013-06-07

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI、PubMed、Scopus

Volume:42

Issue:21

Page Number:7693-7698

ISSN No.:1477-9226

Abstract:A cyano-bridged ferromagnetic {(FeNiII)-Ni-III} alternating chain {[Fe(pzTp)(CN)(3)][Ni(chxn)(2)]}center dot ClO4 center dot H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound 1 had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.