Tetrakis(phthalocyaninato) Rare-Earth-Cadmium-Rare-Earth Quadruple-Decker Sandwich SMMs: Suppression of QTM by Long-Distance f-f Interactions
Release Time:2019-03-09 Hits:
Indexed by: Journal Article
Date of Publication: 2012-06-01
Journal: CHEMISTRY-A EUROPEAN JOURNAL
Included Journals: Scopus、EI、SCIE
Volume: 18
Issue: 25
Page Number: 7691-7694
ISSN: 0947-6539
Key Words: f-f interactions; magnetic properties; phthalocyanines; quadruple-decker complexes; single-molecule magnets
Abstract: Long-distance f-f interactions: Systematic and comparative studies of the magnetic properties of a series of isostructural sandwich-type tetrakis-ACHTUNGTRENUNG(phthalocyaninato) diterbium and monoterbium quadruple-decker complexes clearly reveal the suppression of the quantum tunneling of magnetization by the long-distance intramolecular f-f interactions (see figure). © 2012 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim.