Structural phase transition in a multi-induced mononuclear Fe-II spin-crossover complex

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2015-01-01

Journal: DALTON TRANSACTIONS

Included Journals: Scopus、EI、SCIE

Volume: 44

Issue: 48

Page Number: 20906-20912

ISSN: 1477-9226

Abstract: Herein, we report the investigation of a mononuclear spin-crossover complex [(FeL2)-L-II][ClO4](2) (L = 2,6-bis-{4,4-dimethyl-4,5-dihydrooxazol-2-yl}pyridine). This compound undergoes a structural phase transition around 173 K, accompanying with an abrupt spin-transition process. Interestingly, it exhibits a multi-induced spin-crossover behavior mediated by heat, light, pressure and solvent.

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