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Structural phase transition in a multi-induced mononuclear Fe-II spin-crossover complex

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Indexed by:期刊论文

Date of Publication:2015-01-01

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI、Scopus

Volume:44

Issue:48

Page Number:20906-20912

ISSN No.:1477-9226

Abstract:Herein, we report the investigation of a mononuclear spin-crossover complex [(FeL2)-L-II][ClO4](2) (L = 2,6-bis-{4,4-dimethyl-4,5-dihydrooxazol-2-yl}pyridine). This compound undergoes a structural phase transition around 173 K, accompanying with an abrupt spin-transition process. Interestingly, it exhibits a multi-induced spin-crossover behavior mediated by heat, light, pressure and solvent.

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