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Indexed by:期刊论文

Date of Publication:2015-01-14

Journal:DALTON TRANSACTIONS

Included Journals:PubMed、SCIE、Scopus

Volume:44

Issue:2

Page Number:464-467

ISSN No.:1477-9226

Abstract:It is a challenge to synthesize a porous tubular coordination polymer with magnetic properties. Utilizing [Fe-II(bipy)(CN)(4)](2-) (bipy = 2,2'-bipyridine) as the building block to react with Mn2+, we successfully synthesized a cyano-bridged tubular coordination polymer with dominant ferromagnetic interactions. The inner surface of the heterometallic tube is hydrophilic, whereas the outer surface is hydrophobic. The framework is stable up to 320 degrees C and can adsorb N-2 and CO2. The ferromagnetic interactions were transmitted via the diamagnetic N-C-Fe-II-C-N species between Mn2+ ions in the tube.