Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion
Release Time:2019-03-09 Hits:
Indexed by: Journal Article
Date of Publication: 2012-04-27
Journal: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Included Journals: Scopus、EI、SCIE、PubMed
Volume: 51
Issue: 18
Page Number: 4367-4370
ISSN: 1433-7851
Key Words: charge transfer; electron transfer; magnetic properties; spin crossover; transition metals
Abstract: A light change: A linear cyanido-bridged Fe2Co compound (see picture) exhibits a reversible, thermally induced cooperative charge transfer transition accompanying spin transition and polar-nonpolar transformation in the trinuclear cluster. The change in magnetic properties and polarity could also be induced by irradiation with light. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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